ZBrush is a digital sculpting and painting program for the design of 3D images. It gives you all of the tools needed to quickly sketch out a 2D or 3D concept. You can create realistic renders directly in ZBrush with lighting and atmospheric effects. Designed around a principle of circularity, the menus in ZBrush work together in a non-linear and mode-free method. This facilitates the interaction of 3D models, 2D images, and 2.5D Pixols in a unique manner.
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The program is commercial, to purchase ZBrush kindly follow http://zbrush.software.informer.com/download/?af11ff1d